Bis(diethylamino)(pentafluorophenyl)phosphane - a Push-Pull Phosphane Available for Coordination

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Bis(diethylamino)(pentafluorophenyl)phosphane – a Push–Pull Phosphane Available for Coordination

A facile large-scale synthesis of the “push–pull”-substituted ligand bis(diethylamino)(pentafluorophenyl)phosphane is reported. A selenophosphorane as well as complexes with CuI and PdCl2, can be formed almost quantitatively from suitable starting materials. The PdII complex shows a square-planar coordination with significant distortions of the Cl–Pd–Cl moiety in the solid state. In contrast, t...

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ژورنال

عنوان ژورنال: European Journal of Inorganic Chemistry

سال: 2011

ISSN: 1434-1948

DOI: 10.1002/ejic.201100138